The presence of 23 wt% molybdenum in the alloy makes the passive film stronger kain et al. Stress corrosion cracking scc of duplex stainless steel. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. When sulfides are present in caustic solutions the scc has been reported to occur at lower temperatures.
Stress corrosion cracking facts and how to reduce the. Stress corrosion cracking facts and how to reduce the risk. Stresscorrosion cracking of sensitized type 304 stainless. Stress corrosion cracking results from the conjoint action of three components. Stress corrosion cracking scc is a common issue with many specialty alloys.
Corrosion developed after 4 weeks in the 304 and 304l specimens, and after 32 weeks in the 316l specimen. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. A film of more acidic corrodent solution is raised to ph 1. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Stress corrosion testing of type 304 stainless steel in boiling mgcl 2 at 416k revealed that cracks occurred radially for a circumferential residual stress and circumferentially for a radial residual stress. Pitting corrosion has been reported from household bleach spills on stainless steel 304 type sinks in domestic environments. Past researched about scc of 310s primarily focus on the corrosion mechanism and influence of temperature and corrosive media, but few studies. Stainless steels types 304 and 316 can be considered resistant below 80 degc, up to the limit of solubility.
Pitting corrosion the passive layer on stainless steel can be attacked by certain chemical species. This research was focused on the failure analysis of a cracked ss304 stainless steel elbow from a chemical plant. Stress corrosion cracking scc is a progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment. The stress corrosion cracking scc of aisi 304 and aisi 316 austenitic stainless steels in 0. Type 304 stainless steel an overview sciencedirect topics. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Pitting or crevice corrosion can occur on most stainless steel grades. Corrosionpedia what is stress corrosion cracking scc. Corrosion corrosion is galvanic corrosion of metal surfaces all media phenomenon of corrosion. Transgranular stress corrosion cracking of 304l stainless. Unexpected corrosion of stainless steel in high solids black. Stress corrosion crackingscc is the main corrosion failure mode for 310s stainless steel. Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenancefree service life of the structure.
This paper presents a fusion welding process that was developed for snf canister repair. Localized corrosion and stress corrosion cracking of stainless steels. Austenitic stainless steels crni types 304, 304l, 321, and similar and crnimo types 316, 316l, 316 ti, and similar are susceptible to atmosphericallyinduced stress corrosion cracking aiscc at ambient temperatures if hygroscopic salts such as mgcl 2 or cacl 2 are present on the surface and the air relative humidity rh is in a critical range. The final, definitive version of this document can be found online at. It is not practical to pick one of the factors as the dominant reason for crack development.
Effects of fluoride and other halogen ions on the external. Ae signals came from ligament tearing and plastic deformation of crack tips. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. Influence of high temperature on corrosion behavior of 304. Chloride stress corrosion cracking in austenitic stainless. Influence of chromium depletion on intergranular stress. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Pdf chloride induced stress corrosion cracking of type 304 and. Near the edge of sensitized specimens with residual stress, slight intergranular cracking occurred after 783 hours in pure water. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Atmospheric stress corrosion cracking of stainless steel. Aisi 304 stainless steel is widely used in many applications because of its mechanical and corrosion properties. The potential for stress corrosion cracking scc of welded stainlesssteel interim storage containers for spent nuclear fuel snf has been identified as a high priority data gap.
The resistance of austenitic stainless steels to scc is related to the nickel content of the steel. Mar 11, 2020 this research was focused on the failure analysis of a cracked ss304 stainless steel elbow from a chemical plant. Film and ph effects in the stress corrosion cracking of. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i. Jan 08, 2002 the duplex stainless steels, on the other hand, are more resistant to stress corrosion cracking scc than austenitic grades. Although no stainless steel grade is totally immune.
Scc can occur typically in hot water tanks or swimming pools. Corrosion of unprotected carbon steel occurs even inside reinforced. What forms of corrosion can occur in stainless steels. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design.
Stress corrosion cracking scc is characterized by cracks propagating either. Stress corrosion cracking is the cracking of a susceptible metal under the mixed. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and. Pdf chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in.
Effects of temperature and humidity on atmospheric stress. Austenitic steels of type astm 304 and 316 austenitic steels have limited. The chloride ion cl is the most common of these and is found in everyday materials such as salt and bleach. Stress corrosion cracking of austenitic stainless steel technical bulletin ind tb009 02212020 replaces 011918 two other common specifications are mili24244 and nrc 1. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. Mili24244 is a us dept of defense specification for insulation that is going to be used on the stainless steel pipe and equipment associated with nuclear propulsion. The material used in the present study is 304 stainless steel, the chemical composition of it is shown in table i. Introduction in order to prevent stress corrosion cracking scc of sensitized 304 stainless steel in high temperature pure water, metallurgical, mechanical and environmental countermeasures have been established and some of them have been applied to operating and constructing plants successfully. Highlightstypical scc modes and different crack growth rates were designed. Stainless steels are more resistant to general corrosion compared with carbon steel. Stress corrosion cracking of an austenitic stainless steel. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Stress corrosion cracking of aisi 304 and aisi 316. Escc susceptibility depends on environmental factors.
Detecting and imaging stress corrosion cracking in. For example, copper and its alloys are susceptible to ammonia compounds, mild steels are susceptible to alkalis and stainless steels are susceptible to chlorides. Practical solutions by solutions for people, processes and paper. Burst and continuous ae signals were detected during scc in hightemperature water. Structural failure due to scc can be very unpredictablefailure could occur after as little as a few hours of exposure, or the equipment could continue to function normally for. Atmospheric stress corrosion cracking susceptibility.
Stress corrosion cracking of a 304 stainless steel elbow. Stress corrosion cracking of sensitized type 304 stainless. External stress corrosion cracking escc by sea salt particles can occur in these plant component materials. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Therefore, standard grades such as 304304l and 316316l are very. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. For austenitic stainless steels, stress corrosion cracks.
The effect of hydrogen peroxide on the stress corrosion. Stress corrosion cracking of type aisi 304 stainless steel at room. Insitu monitoring of stress corrosion cracking of 304 stainless steel in hightemperature water by analyzing acoustic emission waveform. Polythionic stress corrosion cracking of stainless steel tube environment. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. The main form of corrosion of stainless steel corrosion surface corrosion, pitting corrosion, crevice corrosion and stress corrosion. While type 304 sensitized stainless steel suffer intergranular attack and scc in the presence of f. Chloride stress corrosion cracking in austenitic stainless steel. Isaacs the stress corrosion cracking of a sensitized type 304 stainless steel has been studied at room. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and. Unexpected corrosion of stainless steel in high solids black liquor service.
There can be a risk of stress corrosion cracking scc. Figures 2,3,4 and 5 show the scc behaviour of type 304 austenitic stainless steel in dilute h 2 so 4 and expressed in terms of percentage elongation to fracture and in terms of reduction in cross sectional area. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Hence the tendency for stress corrosion cracking of the plain 304 or 316 stainless steels in solution annealed condition is not considered to be different from its low carbon varieties. Intergranular stresscorrosion cracking igscc on a sensitized type aisi 304 stainless steel specimen was monitored simultaneously by acoustic emission, elongation measurements, electrochemical. Intergranular stress corrosion cracking igscc of sensitized aisi 304 stainless steel ss was studied in aerated pure water and in chloride solutions with and without sulfide and thiosulfate. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization.
Corrosion resistance of stainless steels corrosion in concrete corrosion problems are not limited to outside surfaces. On the stress corrosion cracking and hydrogen embrittlement. Insitu monitoring of stress corrosion cracking of 304. However, its tendency to corrode in the presence of halide ions limits the applications. The influence of chloride concentration and acidity on the occurrence of stress corrosion cracking s. The elbow was welded with two straight pipes at two ends. There is an additional risk of stress corrosion cracking scc at higher temperatures. Chloride stress corrosion cracking ssina specialty steel.
Austenitic stainless steels are widely used as structural materials for chemical and power plants. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and carbonatebicarbonate solutions. Stress corrosion cracking susceptibility of 304l substrate and. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. Effects of temperature and pressure on stress corrosion. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. The multiple crevice assembly mca method described in astm g4829 and previous studies, was adopted to study the crevice corrosion and stress corrosion cracking behavior of type 304 09a stainless steel. Pitting corrosion is avoided by making sure that stainless steel does not come into prolonged contact with harmful chemicals or by.
Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Intergranular stress corrosion cracking igscc on a sensitized type aisi 304 stainless steel specimen was monitored simultaneously by acoustic emission, elongation measurements, electrochemical. Ammonium hydroxide stainless steela ahow good resistance to all concentrations of ammonia. It has been found that scc resistance can be improved in some cases with the application of compressive stress to the material at risk. There is an additional risk of stress corrosion cracking scc at. Stresscorrosion cracking of sensitized type 304 stainless steel in thiosulfate solutions r.
Introduction stress corrosion cracking scc of austenitic 304 stainless steel in chloride environment is a common problem in industries. Intergranular corrosion of 304 stainless steel during the fabrication of stainless steel components or structures it is possible to degrade the corrosion resistance. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic. Corrosion behavior of austenitic stainless steel in. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Both of type 304 and type 316 stainless steels showed quite similar. Chloride stress corrosion cracking inspectioneering. Stress corrosion cracking british stainless steel association. Stress corrosion cracking of type 304 stainless steel.
Film and ph effects in the stress corrosion cracking of type. Polythionic stress corrosion cracking of stainless steel tube. In 1985, 12 people were killed in uster, switzerland when the concrete roof of a swimming pool collapsed only after thirteen years of use. Stainless steel corrosion pitting corrosion crevice. Sensor requirements for detection and characterization of. Stress corrosion cracking of an austenitic stainless steel in. We examined the effects of temperature and humidity on escc experimentally. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. It is found that the stress vs timetofailure curves for both alloys are divided into three regions that. The potential for stress corrosion cracking scc of welded stainless steel interim storage containers for spent nuclear fuel snf has been identified as a high priority data gap. Direct correlations are made between the extent of chromium depletion at grain boundaries and intergranular stress corrosion cracking igscc of 304 stainless steel during slowstrainrate ssr tensile tests in 288 c airsaturated water.
A key question is the nature of irradiationassisted intergranular cracking at very high dose, i. Stress corrosion cracking of sensitized type 304 stainless steel in thiosulfate solutions r. In this work, hotcell tests and micro structural characterization were performed on type 304 ss from the hexagonal fuel can of the decommissioned ebrii reactor after. Rapid stress corrosion cracking of 304 stainless steel in mgcl 2fecl 3 solutions at 125 c has been shown to occur only when the ph of the corrodent liquid within the crack lay between 1. Stress corrision cracking is a relatively rare form of corrosion, which requires a specific combination of tensile stress, temperature and corrosive species, often the chloride ion, for it to occur. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. This mode of attack is termed stress corrosion cracking scc. According to different requirements resorted to different indicators, generally divided into two main categories. Unexpected corrosion of stainless steel in high solids. The drip procedure from the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to nuclear regulatory commission. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems.
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